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Effects of Different Stabilizers on Sintering Behavior and Microstructure of Zr02 Ceramics

FANG Yihang 1WANG Huanping 1XU Shiqing 1, XIE Hongyan 2WANG Jianwu 2

(1.(1.College of Materials Science and Engineering, China Jiliang University, Hangzhou Zhejiang 310018, China;2.Hangzhou Gaotao Technology Co., Ltd, Hangzhou Zhejiang 310018, China)

Abstract:The sintering behavior and microstructures of ZrO2 ceramics doped with Ce02, MgO and Y2Ohave been investigated. The results showed that the cracks inZrO2 bulks were not inhibited, although the grains could be refined and the volume densities increased with the increase of CeO2.The addition of a proper amount of MgO was useful to inhibit the fracture propagation, and the Mg0-ZrO2 ceramics could be sintered at 1450'C. However, the MgO addition could not refine the grains, and an excessive MgO addition would cause drastic ZrO2 crystal grain growth. Compared with Ce02 and MgO, Y2O3 was the best stabilizer, which not only inhibited the fracture propagation, but also refined the grains of ZrO2ceramics. The optimal Y2O3  doping amount was 3 mol%, and the Y203-ZrO2 ceramics could be sintered at 1550'C.

Key words:Zr02; stabilizer; volume density; microstructure


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