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Effect of Variation in Hydrophilicity and Hydrophobicity on the Water Flux of Ceramic Microfiltration Membranes

HE Rujie ,WU Yefan, ZHOU Jian'er, SHI Jijun, YU Ting, PAN Xia, WEI Fei

(University Key Laboratory of Inorganic Membrane in Jiangxi Province, Jingdezehn Ceramic Institute, Jingdezhen 333001)

Abstract:Ceramic microfiltration membranes unmodified and modified with a titanate coupling agent were characterized by hightemperature pyrolysis gas -chromatography and FTIR. The density of hydroxyl groups on the unmodified and modified membranes was monitored by a nonaqueous titration. After modification, the lipophilic degree increased markedly, and the water absorption ability decreased greatly. In a certain pressure range, the water flux of ceramic microfiltration membranes reduced obviously as the hydrophilicity of inner pore walls in the modified membranes decreased. When the hydrophilicity reached a certain value, the water flux of the ceramic microfiltration membranes tended to be zero.

Keywords:hydrophilicity, hydrophobicity, water flux, hydroxyl, titanate coupling agent


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