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Low-temperature Synthesis of High Rendering BiVO4 Yellow Pigment via Chemical Co-precipitation

ZHANG Xiaojun 1, LI Wen 2, XU Yanqiao 1, WU Qian 1

(1. National Engineering Research Center for Domestic & Building Ceramics, Jingdezhen 333001, Jiangxi, China; 2. Jingdezhen Ceramic University, Jingdezhen 333403, Jiangxi, China)

Abstract: BiVO4 yellow pigment was synthesized by using a template-free chemical co-precipitation method at low temperatures, with bismuth nitrate pentahydrate [Bi(NO3)3•5H2O] and ammonium metavanadate (NH4VO3) as Bi and V resources and deionized water as solvent. Phase composition and morphological characteristics of the samples were studied by means of X-ray diffraction (XRD), Raman and field emission scanning electron microscope (SEM). CIE-L* a* b* color system and UV-vis diffuse reflectance spectra were employed to characterize chromatic properties of the BiVO4 pigment. It is found that the resulting products have monoclinic scheelite-structure and irregular bulk-like morphology with an average particle size of 1.7 μm. Meanwhile, the formation temperature is much lower than that of the conventional solid state method (700 ℃). When the concentration of precursor solution and pH value are 0.05 mol•L−1 and 6, the BiVO4 yellow pigment shows excellent chromatic performance, with L*=76.66, a*=0.22, b*=76.12, which is much higher than that of the commercial BiVO4. Importantly, the as-prepared BiVO4 pigment is applied in polymethyl methacrylate (PMMA) and exhibits excellent color and dispersion properties in the matrix.

Key words: yellow pigment; BiVO4; co-precipitation method; low-temperature synthesis; high rendering

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[1] ZHANG Xiaojun, LI Wen, XU Yanqiao, et al. Low-temperature Synthesis of High Rendering BiVO4 Yellow Pigment via Chemical Co-precipitation [J]. Journal of Ceramics. 2022, 43(6): 1059-1067.
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