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Research Progress of Garnet-type Inorganic Solid Lithium Ion Electrolyte

 LV Xiaojuan, WU Ya’nan, MENG Fanli, ZHAO Hengyang, MA Ruijing, WANG Qingling
(North China Electric Power University (Baoding), Department of Environmental Science and Engineering,
Baoding 071000, Hebei, China)

Abstract: All-solid electrolytes have become the focuses of research in recent years. Among them, the garnet-type all-solid electrolyte Li7La3Zr2O12 is a promising one due to its high ionic conductivity, wide electrochemical window and stability against lithium. The structures of garnet-type inorganic solid electrolytes, preparation methods including solid state method, sol-gel method and co-precipitation method are reviewed in this paper. The modification of solid electrolytes via doping is also systematically researched. The prospective of the solid electrolytes is proposed.

Key words: garnet type; all solid electrolyte; doping; conductivity; lithium ionic conductor

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